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Creators/Authors contains: "Smith, Patrick W"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Chemical Science)
    Organometallic cerium(iv) and thorium(iv) alkynyl complexes were synthesized, and compared experimentally and theoretically. A cerium(iv)trans-influence ligand series was observed and analyzed. 
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    Free, publicly-accessible full text available August 5, 2026
  2. ; ; ; ; ; ; ; ; ; ; et al (, Nature Chemistry)
    Free, publicly-accessible full text available June 1, 2026
  3. ; ; ; ; ; ; ; ; ; ; et al (, Chemical Science)
    X-ray absorption spectroscopy and variable temperature magnetometry show evidence of 4f-orbital mixing in Cp′3Eu, which increases its magnetic susceptibility. 
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  4. ; ; ; ; ; ; ; ; (, Journal of the American Chemical Society)
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  5. ; ; ; ; (, Journal of the American Chemical Society)
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  6. ; ; (, Chemical Science)
    null (Ed.)
    Cationic iron complexes [Cp*( i Pr 2 MeP)FeH 2 SiHR] + , generated and characterized in solution, are very efficient catalysts for the hydrosilation of terminal alkenes and internal alkynes by primary silanes at low catalyst loading (0.1 mol%) and ambient temperature. These reactions yield only the corresponding secondary silane product, even with SiH 4 as the substrate. Mechanistic experiments and DFT calculations indicate that the high rate of hydrosilation is associated with an inherently low barrier for dissociative silane exchange (product release). 
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  7. ; ; ; ; (, Journal of the American Chemical Society)
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